环合法构建金刚烷四酮骨架的合成方法研究
关键词 金刚烷酮 1,5-环辛二烯 金刚烷四酮骨架
毕业设计说明书（毕业论文）外文摘要
Title Research on the synthesis of adamantane tetrone framework by cyclization
Abstract
Adamantanone compound is a kindle of novel fine chemicals. And it was widely used in many fields, such as medicine, materials and so on. The structure, properties, synthesis methods and the application of the adamantane were introduced in detail. Also, the synthesis and current use of the adamantanone and adamantanol as well as their derivatives were presented. Two ways were designed to construct the skeleton of adamantane tetraone. With 1,5-cyclooctadiene as raw material, 2,2,6,6-diethylenedioxyadamantane-4,8-diol was synthesized. And only the method which undergo addition with borane was of higher yield. Moreover, the steps of it were simple and the raw material is readily available, as a result of which it is a promising method to establish the skeleton of adamantanone.
Keywords Adamantanone 1,5 - cyclooctadiene Adamantine tetrone skeleton
目 次
1 绪论 1
1.1 金刚化学的形成与发展 1
1.2 金刚烷的结构 1
1.3 金刚烷的性质 2
1.3.1 金刚烷的物理性质 2
1.3.2 金刚烷的化学性质 2
1.4 金刚烷的合成 4
1.5 金刚烷及其衍生物的应用 6
1.5.1 医药领域 6
1.5.2 军事与航空领域 6
1.5.3 功能材料领域 6
1.5.4 精细化工领域 7
1.6 金刚烷酮简介 7
1.6.1 金刚烷及其衍生物的用途 7
1.6.2 金刚烷酮的合成 8
1.7 金刚烷醇简介 9
1.7.1 金刚烷醇及衍生物的用途 9
1.7.2 金刚烷醇的合成现状 10
2 2,2,6,6-二乙撑二氧基-4,8-金刚烷二醇的合成 12
2.1 引言 12
2.2 实验药品与仪器 12
2.2.1 实验药品 12
2.2.2 实验仪器 13
2.3 1,5-环辛二醇的合成 13
2.4 1.5-环辛二酮的合成 14
2.5 2-甲酰基-1,5-环辛二酮的合成 15
2.6 9-羟基双环[3.3.1]壬烷-2,6-二酮的合成 16
2.7 9-羟基-3-甲酰基双环[3.3.1]壬烷-2,6-二酮的合成 16
2.8 4,8-二羟基金刚烷-2,6-二酮的合成 17
2.9 2,2,6,6-二乙撑二氧基-4,8-金刚烷二醇的合成 18
3 硫杂金刚烷合成2,2,6,6-二乙撑二氧基-4,8-金刚烷二醇 19
3.1 引言 19
3.2 实验药品与仪器 20
3.2.1 实验药品 20
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