卟啉复合薄膜的组装+文献综述
毕业论文关键词：卟啉，自导向组装，薄膜，结构，性能。
Assembly of porphyrin composite films
Abstract: Porphyrin are a kind of macro cyclic conjugated aromatic compounds with favorable optoelectronic properties and biological activity. In recent years, considerable attention has been paid on porphyrin compounds owing to their potential applications in bionics, life sciences, medicine, materials science, electrochemistry, photophysics and chemistry, analytical chemistry and organic chemistry. At the same time, on account of the characteristics of well-order, stable, various properties and pre-designed structure, self-assembled film of porhyrin has been widely applied in the electronic and optical devices, chemical sensors, biological sensors, catalysis, and other research fields. It has been the focus of considerable research activity. In this thesis, a new kind of porphyrin monomer with special reactivity was designed and prepared. By using the reactivity of axial and peripheral substituent of the monomer, two and three-dimensional stable thin films of pophyrin were fabricated by self-directed assembly of the monomers. The achieved porphyrin films were with great advantages of controlled growth direction, thickness and high photoelectric conversion efficiency. The technique by combining porphyrin and self-directed assembly was very important to construct orderly functional thin films of porphyrins.
Keywords: Porphyrin, Assembly, Thin films, Structure, Properties.
目录
卟啉复合薄膜的组装 II
1 前言 1
1.1 卟啉类化合物 1
1.1.1 卟啉类化合物的结构 2
1.1.2 卟啉及金属卟啉类化合物 2
1.2 卟啉以及卟啉类化合物的应用 3
1.2.1 癌症的诊断与治疗 3
1.2.2卟啉在太阳能电池中的应用 4
1.2.3卟啉在生命科学中的应用 4
1.3 自组装技术 5
1.3.1 自组装膜的研究和应用 6
1.3.2 自组装膜的制备 6
1.3.3 自组装膜成膜的影响因素 7
1.3.4 自组装膜的表征方法 8
2 实验部分 9
2.1 实验试剂 9
2.2 实验仪器 10
2.3 实验方法 12
2.3.1 吡咯的前处理 12
2.3.2 金属卟啉的合成 12
2.3.3酰氯化、硅烷化 13
2.3.4卟啉复合薄膜的组装 13
3 结果与讨论 14
3.1 反应现象 14
3.2 四羧基苯基卟啉钴及其硅烷化卟啉的紫外可见光谱图 15
3.3硅烷化单体以及卟啉复合薄膜傅立叶变换红外光谱图 16
3.5卟啉复合薄膜荧光光谱图 18
3.6卟啉复合薄膜的固体紫外可见漫反射光谱图 19
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