Dehydrogenation of isobutane to isobutene process design
Abstract:Isobutane catalytic dehydrogenation technology is one of the main way to solve insufficient isobutylene.It is the key to the C4 comprehensive utilization to be concerned by the all over the word. C4 resources are rich in our country, while isobutylene is currently one of the scarce resources in our country, with isobutylene as resources of fine chemical industry is developing rapidly, demand is growing rapidly, and isobutane catalytic dehydrogenation isobutylene is one of the main ways to solve the shortage of isobutylene. At present, the domestic many institutions of higher learning are for isobutane dehydrogenation catalyst for laboratory research, foreign representative process mainly include: mobile bed Oleflex UOP process and Lummus company Catofin fixed bed process. Oleflex process using load platinum alumina catalyst, the catalyst continuous regeneration process for moving bed of proprietary UOP; Catofin process using chrome oxide catalyst, process with multiple reactor, catalyst regeneration to switch. This design in accord with national conditions, advanced technology and easy, the principle of economy, environmental protection, in catalytic cracking of C4 isobutane as raw material, with Cr2O3/Al2O3 catalyst, using fixed bed reactor, and the catalytic dehydrogenation of isobutane processes for material balance and heat balance, on the part of the equipment design and selection, the resulting isobutylene products subject to the technological requirements.
Key words: catalytic dehydrogenation;isobutylene;material balance;heat balance;equipment selection
目录
1 绪论 1
1.1 项目概况[12] 1
1.2 设计的目的和意义 2
1.3 设计依据 2
1.4 项目背景 2
1.4.1 能源问题 2
1.4.2 混合C4中异丁烷的含量 3
1.4.3 我国异丁烷的现状[11] 3
1.5 国内外有关工艺技术进展 4
1.5.1 国内工艺研究进展[10] 4
1.5.2 国外工艺研究概述[11] 4
1.6 设计的范围、装置组成及建设规模 8
1.6.1 设计的范围 8
1.6.2 设计重点 8
1.6.3 生产和辅助车间设置 8
1.6.3 建设规模 9
2 工艺论证 10
2.1 工艺路线概述 10
2.2 脱氢路线的选择[14] 10
2.3 催化剂的选择[14] 12
3 工艺流程 14
3.1 异丁烷脱氢工艺流程 14