硼基纳米高能燃料的制备与燃烧性能
关键词 贫氧推进剂 硼燃料 液相法 纳米复合粒子 Title Preparation and combustion properties of boron based nano-high-energy fuel
Abstract
In this paper, the preparation of boron-based nano-high-energy fuel rich
propellant combustion performance. Nanometer B/Fe2O3 、B/NiO and Mg/B2O3
were prepared by sol-gel synthetic approach. Nanometer B/CuO was prepared
by liquid precipitation method. Nanometer B/Ni was prepared by electroless
plating method, and scanning electron microscopy, thermal gravimetric
analysis were characterized. The results showed that the nanometer B/Fe2O3
larger particle size, particle irregular; impure nanometer B/NiO powder,
coated with thick, serious agglomeration; spherical nanometer B/CuO powder
particles larger diameter; incomplete coated nanometer B/Ni powder, bare
fine boron powder obvious agglomeration; particle crystallization is
incomplete the nanometer Mg/B2O3 powder, spherical particles. Obtained
boron composite particles application in propellants and combustion
temperature and burning rate test results show that boron composite
particles of the propellant combustion performance relative to non-coated
boron powder propellant With some improvement.
目 次
引言 1
1.1 背景与意义 1
1.2 国内外研究现状 3
1.2.1 贫氧推进剂的国内外研究现状 3
1.2.2 贫氧推进剂燃料的国内外研究现状 5
1.2.3 硼燃料的国内外研究现状 5
1.3 本文研究工作 6
本章参考文献 . 7
硼基高能燃料的性能设计 9
2.1 高热剂燃烧性能的计算方法 9
2.1.1 高热剂反应方程式吉布斯自由能的计算 9
2.1.2 高热剂燃烧反应热效应的计算 9
2.1.3 高热剂燃烧温度的计算 . 10
2.2 硼基高能燃料组分选择与理论配方计算 . 11
本章参考文献 12
硼基纳米复合燃料制备工艺设计 . 13
3.1 纳米单质的制备工艺综述 . 13
3.1.1 纳米银单质的制备工业综述 . 13
3.1.2 纳米铁单质的制备工业综述 . 15
3.1.3 纳米铜单质的制备工业综述 . 16
3.1.4 纳米镍单质的制备工艺综述 . 17
3.2 纳米氧化物的制备工艺综述 . 17
3.2.2 纳米氧化镍的制备工艺综述 . 18
3.2.3 纳米氧化铜的制备工艺综述 . 19
3.2.4 纳米氧化硼的制备工艺综述 . 19
3.3 纳米级单质-氧化物复合粒子的制备综述 20
3.3.1 纳米 Al/ZnO复合粒子的制备综述 20