壁纸水性油墨的研制+文献综述
关键词：水性树脂；性能；干燥速度；光泽度；粘度；水性上光油
Wallpaper with the development of water-based ink
Abstract:This paper use the OP - 21, SDS and MS - 1 emulsifier to produce the water-borne tertiary carbonic acid vinyl ester crosslinking acrylate resin, water-borne ketone hydrazine crosslinking acrylate resin, and N-methylol acrylamide aqueous crosslinking acrylate resin by semi-continuous core - shell emulsion polymerization respectively，to complete the determination of various water-based resin solidss content, water absorption rate, viscosity, water resistance，gloss performance，drying time and other properties as well as on all kinds of resins for infrared characterization of lipid membranes.Finally,take emulsion as forming material,adding appropriate additives to produce the waterborne glazing oil,then measure the properties of viscosity, gloss performance,drying time, frictional resistance,water resistance,etc.The research shows that N-methylol acrylamide aqueous crosslinking acrylate resin as film forming material of waterborne glazing oil has excellent gloss performance, strong resistance to water, alcohol, acid, alkali, frictional resistance.
Keywords: water-borne resin;performance;drying time;gloss;viscosity;water-borne glazing oil
目 录
1 绪论 1
1.1 叔丙体系的概述 1
1.2 酮肼交联体系的概述 3
1.3 N-羟甲基丙烯酰胺交联丙烯酸酯体系的概述 4
1.4 乳化剂概述 4
1.5 成膜助剂的概述 5
1.6 水性流平剂的概述 6
1.7 水性流变助剂的概述 6
1.8泡沫控制助剂的概述 7
1.9研究意义和目的 7
2 实验 8
2.1 原料名称﹑规格和来源 8
2.2 水性树脂反应机理 8
2.2.1 水性叔丙树脂反应机理 9
2.2.2 水性酮肼交联丙烯酸酯树脂反应机理 9
2.2.3 水性N-羟甲基丙烯酰胺交联丙烯酸酯树脂反应机理 10
2.3 水性树脂合成基本反应及设计的Tg 10
2.3.1 水性叔丙树脂基本反应 10
2.3.2 水性酮肼交联丙烯酸酯树脂基本反应 11
2.3.3 水性N-羟甲基丙烯酰胺交联丙烯酸酯树脂基本反应 13
2.3.4 共聚物Tg的计算方法及各体系的Tg 14
2.4 水性树脂合成制备工艺 16
2.4.1 水性叔丙树脂合成制备工艺 16
2.4.2 水性酮肼交联丙烯酸酯树脂合成制备工艺 16
2.4.3 水性N-羟甲基丙烯酰胺交联丙烯酸酯树脂合成制备工艺 16
2.4.5 水性上光油的制备工艺 17
2.5 性能测试 17
2.5.1 固含量的测定 17
2.5.2 吸水率的测定 17
2.5.3 红外测试 18
2.5.4 耐乙醇、耐碱、耐酸、耐水性（浸泡法） 18
2.5.5 干燥时间的测定 18